© Journal Of Chemical Society Of Nigeria (jcsn) . 2012. Vol. 37 No. 2
Publisher: Chemical Society of Nigeria
Synthesis and Complexation of N'-[-PHENYLMETHYLIDENE]Benzenecarbothio Hydrazide With Co(II), Ni(II), Cu(II) and Zn(II) Metal Ions.
I. E. Otuokere, E. N.orjiako
KEYWORDS: N'-[-phenylmethylidene]benzenecarbothiohydrazide, ligand, complexes, square-planar geometry
ABSTRACT:A novel ligand, N'-[-phenylmethylidene]benzenecarbothiohydrazide was synthesized by the reaction of benzenecarbothiohydrazide and benzaldehyde in 1:1 ratio. The Co(II), Ni(II), Cu(II) and Zn(II) derivatives of N'-[-phenylmethylidene]benzenecarbothiohydrazide were also synthesized. The ligand and metal complexes were characterized based on molecular weight, IR, electronic spectra, 1HNMR and 13CNMR. Their spectroscopic characterization suggested coordination of the ligand to the metal ions through the >C=N and C=S. The complexes with [M(L)2] showed a square-planar geometry.
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